- 펜톤 산화법에 의한 PCE 오염 토양의 정화
- Remediation of Perchloroethylene Contaminated Soil by Fenton Oxidation
- ㆍ 저자명
- 이병대,김영찬,Lee. Byung-Dae,Kim. Yeoung-Chan
- ㆍ 간행물명
- 한국유화학회지
- ㆍ 권/호정보
- 2005년|22권 2호|pp.136-141 (6 pages)
- ㆍ 발행정보
- 한국유화학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
This paper presents applicability of Fenton oxidation to perchloroethylene(PCE) contaminated soil. The initial concentration of PCE was 187mg/kg and Fenton oxidation conditions were 1.0M $H_2O_2$ and 0.5M $Fe^{2+}$. More than 97% of PCE decomposition and 98% of dechlorination were obtained within 5 hrs. It was found that the decomposition of PCE by Fenton oxidation was followed pseudo first order and its reaction coefficient was 0.78 $hr^{-1}$. GC-MS and GC-ECD analysis of reaction intermediates confirmed only the presence of trichloroacetic acid(i.e., 1.0% of initial PCE concentration). Under Fenton oxidation conditions, it was proposed that PCE was decomposed not simultaneously but one by one.