The recent Bistable Nematic ($BiNem^{(R)}$) LCD technology presents long term bistability, high level passive matrix multiplexing, gray levels capabilities and high optical quality. The $BiNem^{(R)}$ device, based on anchoring breaking, needs specific low anchoring strength materials - alignment layers and liquid crystal mixtures. We present here our approach to develop nematic mixtures with wide enough temperature range and low zenithal anchoring energy.