A new numerical scheme solving two-phase flow, the Hybrid VOF method for improved free surface capturing has been developed by combining a volume capturing VOF method with the Level-Set reinitialization procedure. For validation, the proposed method is applied to 3-D bubble rising problem, dam breaking and the free surface flow around a commercial container ship. The calculated results by using the Hybrid VOF method with the two previously applied VOF formulations are compared with available numerical and experimental data. It is found that the new method provides more reasonable results than the two previous ones.