- 아지드기로 양말단 변성된 저분자량 Glycidyl Azide Polymer의 합성
- ㆍ 저자명
- 민병선,Min. Byoung-Sun
- ㆍ 간행물명
- 韓國軍事科學技術學會誌
- ㆍ 권/호정보
- 2005년|8권 1호|pp.69-80 (12 pages)
- ㆍ 발행정보
- 한국군사과학기술학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
A synthesis of azide-terminated glycidyl azide polymer, GAP-A, was carried out by tosylation and azidation of polyepichlorohydrin(PECH) prepared by cationic ring-opening polymerization. Polyepichlorohydrin was prepared by cationic activated monomer polymerization using ethylene glycol and $BF_3{cdot}OEt_2$ as an initiator and a catalyst at $~10^{circ}C$. Tosylation of polyepichlorohydrin was performed using traditional TsCl/pyridine method and was also carried out using TsCl/amine catalysts to reduce the reaction time significantly. Azidation of tosyl-terminated PECH(OTs-PECH) was performed using $NaN_3$ as an azidation reagent in DMF solvent at high temperature and was unexpectedly completed within 2 hours.