In the present study, the effect of blade rotation on blade heat transfer is investigated by comparing with the heat transfer results for the stationary blade. The experiments are conducted in a low speed annular cascade with a single stage turbine and the turbine stage is composed of sixteen guide vanes and blades. The chord length and the height of the tested blade are 150 mm and about 125 mm, respectively. The blade has a flat tip and the mean tip clearance is 2.5% of the blade chord. A naphthalene sublimation method is used to measure detailed mass transfer coefficient on the blade. For the experiments, the inlet Reynolds number is $Re_c=1.5{ imes}10^5$, which results in the blade rotation speed of 255.8 rpm. Blade rotation induces a relative motion between the blade and the shroud as well as a periodic variation of incoming flow. Therefore, different heat/mass transfer patterns are observed on the rotating blade, especially near the tip and on the tip. The relative motion reduces the tip leakage flow through the tip gap, which results in the reduction of the tip heat transfer. However, the effect of the tip leakage flow on the blade surface is increased because the tip leakage vortex is formed closer to the surface than the stationary case. The overall heat/mass transfer on the shroud is not affected much by the blade rotation.