Generally, biped walking is difficult to control because a biped robot is a nonlinear system with various uncertainties. In this paper, we propose a hybrid sliding-mode control method using a WNN uncertainty observer for stable walking of the 5-link biped robot with model uncertainties and the external disturbance. In our control system, the sliding mode control is used as main controller for the stable walking and a wavelet neural network(WNN) is used as an uncertainty observe. to estimate uncertainties of a biped robot model, and the error compensator is designed to compensate the reconstruction error of the WNN. The weights of WNN are trained by adaptation laws that are induced from the Lyapunov stability theorem. Finally, the effectiveness of the proposed control system is verified through computer simulations.