The flame image processing and analysis system has been investigated for the optimal pulverized coal firing of thermal power plant, especially for lower nitrogen oxide generation and more safe operation. We aimed at gaining the relationship between burner flame image information and emissions of nitrogen oxide and unburned carbon in furnace utilizing the flame image processing methods, by which we quantitatively determine the condition of combustion on the individual humors. Its feasibility test was undertaken with a pilot furnace for coal firing, through which the system was observed to be effective for the monitoring of the combustion condition of pulverized coal firing boilers.