- Au/TiO2 core-shell 나노입자의 합성에 있어서 Au 나노입자의 분산특성에 미치는 Mercaptoundecanoic acid (MUA)의 피복 효과
- ㆍ 저자명
- 유연태,김병규,Yu. Yeon-Tae,Kim. Byoung-Gyu
- ㆍ 간행물명
- 한국재료학회지
- ㆍ 권/호정보
- 2006년|16권 12호|pp.754-760 (7 pages)
- ㆍ 발행정보
- 한국재료학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Mercaptoundecanoic acid (MUA) has been used to enhance the dispersity of Au nanoparticles in organic solvent and the affinity between the Au nanoparticles surface and titanium dioxide shell in the synthesis of $Au/TiO_2$ core-shell composite nanoparticles. The dispersity of the MUA-coated Au nanoparticles in ethanol aqueous solution with different concentration of $H_2O$ was investigated by UV-Vis. absorption spectrum and the coating amount of MUA was varied from 0.02 mM to 1.0 mM. The MUA-coated Au nanoparticles were highly dispersed in pure $H_2O$ in the wide range of the coating amount of MUA. On the contrary, the MUAcoated Au nanoparticles showed an enhanced stability in the ethanol/$H_2O$=8/2 mixed solution only when the coating amount of MUA was 0.05 mM, and in the ethanol/$H_2O$=7/3 mixed solution when the coating amount of MUA was in the range from 0.02 mM to 0.17 mM. From this systematic study, it can be inferred that the stability and the dispersibility of Au nanoparticles in organic solvents are highly sensitive towards the amount of MUA coating.