Corrosion of reinforcing steel bars is a major concern for ocean engineers when reinforced concrete structures are exposed to marine environments. Evaluating the degree of corrosion and corrosion-induced defects is extremely necessary to pursue a proper retrofit or rehabilitation plan for reinforced concrete structures. A promising inspection should be carried out for the evaluation, otherwise the retrofit or rehabilitation process would be useless. Nowadays, ultrasonic guided wave-based inspection techniques become quite promising for the inspection, mainly because of their long-range propagation capability and their sensitivity to different types of defects or conditions. Evaluating haw the guided waves response to the different types of defects or conditions is quite challenging and important. This study shows how surface conditions of reinforcing bars and a corrosion-induced defect, separation, affect guided wave propagation in reinforced concrete. Experiments and associated signal analysis show the sensitivity of guided waves to the surface conditions, as well as the amounts of separation at the interface between. concrete and steel bar.