Based on the practical process engineering design and commissioning and startup operation experiences focused on chemical process safety, the comprehensive review of engineering design and installation of the thermal relief valve with its surrounding facility in a chemical plant piping system is provided to enhance the better understanding of the piping system of characteristics of thermal relief valve which is comprised of the theoretical approach, correlation in terms of temperature and pressure increase caused by external heat supply in a piping system, consideration of thermal relief valve engineering design, pressure relieving system of serial thermal relief valves and exception of their installation. It is earnestly suggested that following topic should be implemented during thermal relief valve engineering design, installation and normal operation as well.