Numerical analysis about atomization and wall impingement process of hollow-cone fuel spray is performed by a modified KIVA code with hybrid model. The atomization process is modeled by using hybrid breakup model that is composed of Linearized Instability Sheet Atomization(LISA) model and Aerodynamically Progressed Taylor Analogy Breakup(APTAB) model. The Gosman model, which is based on the droplet behaviors after impingement determined by experimental correlations, is used for spray-wall impingement process. The LIEF technique was used to compare the results with those of experiment. The calculations and experiments are carried out at the ambient pressures of 0.1 MPa and 0.5 MPa and the ambient temperature of 293K. It was found that the calculated results show satisfactory agreement with experimental ones.