New methods of nano sized material and composite coating preparations have been considered on the base of mathematical model of abrasion reaction interaction of milling and grinding bodies in planetary centrifugal mill. The essence of the method is the abrasive and oxidative wear of the milling bodies and amorphous (better inert) additives. Interactions between them has been supplied the necessary impulse of pressure and temperature on the impact frictional contacts and promoted chemical processes. The offered method can find application for such processing as sintering and geological minerals opening.