As the exhaustion of petroleum resources and air pollution problems are getting serious recently, there are growing interests in premixed diesel engines which have the potential of achieving a more homogeneous mixture near TDC compared to conventional diesel engines. Early studies have shown that the fuel injection frequency and spray angle affected the mixture formation and combustion in a HCCI(Homogeneous Charge Compression Ignition) engine. Therefore, the purpose of this study is to investigate the relationship between combustion and mixture formations by injection timing and frequency using a narrow angle injector, NADI (Narrow Angle Direct Injection). In this study, we found that the fuel injection timing and injection frequency affect the mixture formations and then affect combustion in the HCCI engine.