The existing numerical approximations of convection flux, especially the spatial higher-order difference schemes, in unstructured cell-centered finite volume methods are examined in detail with each other and evaluated with respect to the accuracy through their application to a 2-D benchmark problem. Six higher-order schemes are examined, which include two second-order upwind schemes, two central difference schemes and two hybrid schemes. It is found that the 2nd-order upwind scheme by Mathur and Murthy(1997) and the central difference scheme by Demirdzic and Muzaferija(1995) have more accurate prediction performance than the other higher-order schemes used in unstructured cell-centered finite volume methods.