- Sodium Borohydride의 수소발생을 위한 다공성 Co-P 촉매 개발
- ㆍ 저자명
- 조근우,엄광섭,권혁상,Cho. Keun-Woo,Eom. Kwang-Sub,Kwon. Hyuk-Sang
- ㆍ 간행물명
- 한국수소 및 신에너지학회 논문집
- ㆍ 권/호정보
- 2006년|17권 4호|pp.448-453 (6 pages)
- ㆍ 발행정보
- 한국수소및신에너지학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Porous Co-P catalysts electroplated on Cu in chloride based solution with an addition of $NaH_2PO_2$ and glycine were developed for hydrogen generation from alkaline $NaBH_4$ solution. The microstructures of the Co-P catalysts and their hydrogen generation properties were analyzed as a function of cathodic current density and plating time during the electrodeposition. Amorphous Co-P electrodeposits with porous structure was formed on Cu at cathodic current density of $0.05;A/cm^2$, and showed very high hydrogen generation rate in alkaline $NaBH_4$ solution due to an increase in the surface area of the catalyst as well as the catalytic activity. The Co-P catalyst, which was obtained at cathodic current density of $0.05;A/cm^2$ for 5 min, exhibited the best hydrogen generation rate of 2290 ml/min.g-catalyst in 1 wt. % NaOH+10 wt. % $NaBH_4$ solution at $30^{circ}C$.