The present study has been conducted to investigate the effects of rotation on heat/mass transfer and pressure drop characteristics in a two-pass square duct with and without discrete ribs. For stationary cases, the heat/mass transfer on the surfaces with and without discrete ribs is almost the same or reduced. For rotating cases, the gap flow affects differently the heat/mass transfer on leading and trailing surfaces with discrete ribs. On the leading surface of the first pass, the heat/mass transfer is slightly enhanced due to generating strong gap flow. On the trailing surface of the first pass, however, the heat/mass transfer is much decreased because the gap flow disturbs impingement of main flow. The phenomenon, that is, the heat/mass transfer discrepancy between the leading and trailing surfaces is distinctly presented with the increment of rotation number. The friction losses on each surface with discrete ribs are reduced because the blockage ratio decreases for both non-rotating and rotating cases. Therefore, high thermal performance appears in a duct with discrete ribs.