This paper optimizes the access probabilities (APs) in a network resource allocation scheme based on access probabilities in order that the waiting time and the blocking probability are minimized under the given constraints, and obtains its performance. In order to optimize APs, an infinite number of balance equations is reduced to a finite number of balance equations by applying Neuts matrix geometric method. And the nonlinear programming problem is converted into a linear programming problem. As a numerical example, the performance measures of waiting time and blocking probability for optimal access probabilities and the maximum utilization under the given constraints are obtained. And it is shown that the scheme with optimal APs gives more performance build-up than the strategy without optimization.