The pattern recognition of the complicated grasping operation based on electroencephalography (simply named as EEG) is very helpful on realtime control of the robotic hand. In the paper, a new spectral feature analysis method based on Band Pass Filter (simply named as BPF) and Power Spectral Analysis (simply named as PSA) is presented for discriminating the complicated grasping operations. By analyzing the spectral features of grasping operations with the use of the two-channel EEG measurement system and the pattern recognition of the BP neural network, the degree of recognition by the traditional spectral feature method based on FFT and the new spectral features method based on BPF and PSA could be compared. The results show that the proposed method provides highly improved performance than the traditional one because the new method has two obvious advantages such as high recognition capability and the fast learning speed.