Learning behaviors of a radial basis function network (RBFN) using a singular value decomposition (SVD) and stochastic gradient (SG) algorithm, together named RBF-SVD-SG, for odor sensing systems are analyzed, and a fast training method is proposed. RBF input data is from a conducting polymer sensor array. It is revealed in this paper that the SG algorithm for the fine-tuning of centers and widths still shows ill-behaving learning results when a sufficiently small convergence coefficient is not used. Since the tuning of centers in RBFN plays a dominant role in the performance of RBFN odor sensing systems, our analysis is focused on the center-gradient variance of the RBFN-SVD-SG algorithm. We found analytically that the steadystate weight fluctuation and large values of a convergence coefficient can lead to an increase in variance of the center-gradient estimate. Based on this analysis, we propose to use the least mean square algorithm instead of SVD in adjusting the weight for stable steady-state weight behavior. Experimental results of the proposed algorithm have shown faster learning speed and better classification performance.