Dry Media Reaction Procedure for Synthesis of α,β-Unsaturated Acids, α-Cyanoacrylonitriles and α-Cyanoacrylates via Knoevenagel Condensation Using NaHSO<SUB>4</SUB>·SiO<SUB>2</SUB> Catalyst

Dry Media Reaction Procedure for Synthesis of α,β-Unsaturated Acids, α-Cyanoacrylonitriles and α-Cyanoacrylates via Knoevenagel Condensation Using NaHSO₄·SiO₂ Catalyst
Dry Media Reaction Procedure for Synthesis of α,β-Unsaturated Acids, α-Cyanoacrylonitriles and α-Cyanoacrylates via Knoevenagel Condensation Using NaHSO₄·SiO₂ Catalyst

ㆍ 저자명: Gopalakrishnan. M.,Sureshkumar. P.,Kanagarajan. V.,Thanusu. J.,Thirunavukkarasu. S.
ㆍ 간행물명: 대한화학회지
ㆍ 권/호정보: 2007년|51권 4호|pp.346-351 (6 pages)
ㆍ 발행정보: 대한화학회
ㆍ 파일정보: 정기간행물|ENG|
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ㆍ 주제분야: 기타

이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.

서지반출

영문초록

NaHSO4·SiO2를 사용하는 solvent-free 조건하에서 E-geometry를 가진 α,β의 불포화산, α-Cyanoacrylonitriles 와 α-Cyanoacrylates의 효율적인 입체선택적 반응을 수행하였다.

기타언어초록

Efficient stereoselective synthesis of α,β-Unsaturated acids, α-Cyanoacrylonitriles and α-Cyanoacrylates has been carried out in the presence of NaHSO4·SiO2 under solvent?free conditions with an E-geometry.

키워드

Knoevenagel축합 Arylidene 화합물 Solvent-free solid-state 반응 Silica Gel Supported Sodium Hydrogen Sulphate Knoevenagel Condensation Arylidene Compounds Solvent-free Solid-state Reactions (E)-3-(2-butyl-4-chloro-1H-imidazol-5-yl)acrylic Acid Microwave Irradiation $NaHSO_4{cdot}SiO_2$

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