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Synthesis of CaS:Eu2+ Phosphor by using a Sealing Vessel and its Photoluminescence Properties
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  • Synthesis of CaS:Eu2+ Phosphor by using a Sealing Vessel and its Photoluminescence Properties
  • Synthesis of CaS:Eu2+ Phosphor by using a Sealing Vessel and its Photoluminescence Properties
저자명
Yoo. Hyoung-Sun,Park. Bong-Je,Kang. Jong-Hyuk,Im. Won-Bin,Jeon. Duk-Young
간행물명
Transactions on electrical and electronic materials
권/호정보
2007년|8권 6호|pp.255-259 (5 pages)
발행정보
한국전기전자재료학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

We have synthesized $CaS:Eu^{2+}$ phosphor by using a sealing vessel and evaluated its photoluminescence properties. The method using a sealing vessel is simple and economical in comparison with other methods reported up to date. As an activator concentration was increased from 0.1 mol% to 4 mol%, the main emission wavelength of the phosphor was increased from 642 nm to 651 nm due to the crystal field splitting of 5d levels of $Eu^{2+}$ ion. Although the same amount of $Eu_2O_3$ was used, the concentration of the activator ions, which were reduced from $Eu^{3+};to;Eu^{2+}$ and substituted $Ca^{2+}$ ions, was increased with increase of firing temperature. Therefore, the main emission wavelength was also. shifted from 645 nm to 651 nm with increase of firing temperature from $1100^{circ}C;to;1300^{circ}C$. The critical distance($R_{c1}=20.65;{AA}$) between $Eu^{2+}$ ions calculated from the critical concentration was well matched with that($R_{c2}=19.17;{AA}$) calculated from the Dexter formula.