In this paper, we have propose a preamble structure and synchronization/channel estimation method for UWB-MIMO which has 960Mbps transmit rate. The proposed structure is a compatible preamble structure for synchronization/channel estimation used by MIMO in MB-OFDM(Multi-Band OFDM) systems that are one of the standard systems of MBOA. The system is compatible with MB-OFDM using the proposed preamble structure. In this paper, we argue the problem in receiver part used by MIMO technique. And we simulate the proposed preamble for using synchronization/channel estimation. The simulation result shows the same performance compared with single receiver antenna.