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Study on Indium-free and Indium-reduced thin film Solar absorber materials for photovoltaic application
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  • Study on Indium-free and Indium-reduced thin film Solar absorber materials for photovoltaic application
  • Study on Indium-free and Indium-reduced thin film Solar absorber materials for photovoltaic application
저자명
Kim. Kyoo-Ho,Wibowo. Rachmat Adhi
간행물명
신재생에너지
권/호정보
2007년|3권 4호|pp.54-62 (9 pages)
발행정보
한국신재생에너지학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

In this paper, we report the research highlight on the preparation and characterization of Indium-free $Cu_2ZnSnSe_4$ and Indium-reduced $CulnZnSe_2$ thin films in order to seek the viability of these absorber materials to be applied in thin film solar cells. The films of $Cu_2ZnSnSe_4;and;CulnZnSe_2$ were prepared using mixed binary chalcogenides powders. It was observed that Cu concentration was a function of substrate temperature as well as CuSe mole ratio in the target. Under an optimized condition, $Cu_2ZnSnSe_4;and;CulnZnSe_2$ thin films grew with strong [112]. [220/204] and [312/116] reflections. Both $Cu_2ZnSnSe_4;and;CulnZnSe_2$ films were found to exhibit a high absorption coefficient of $104^4cm^{-1};Cu_2ZnSnSe_4$ film showed a band gap of 1.5eV which closes to the optimum band gap of an ideal solar absorber for a solar cell. On the other side, an increase of optical band gap from 1.0 to 1.25eV was found to be proportional with an increase of Zn concentration in the $CulnZnSe_2$ film. All films in this study revealed a p-type semiconductor characteristic.