Skid mark and coefficient of friction are usually utilized to calculate the velocity and behavior of vehicles. For a critical case such as traffic accident reconstruction, however, the initial velocity of the car should be calculated precisely. In this study, the skid marks on dry asphalt pavement were measured, and the velocity at brake onset was precisely recovered. A passenger car with new tires and non-contact optical speedometer were set up for the tests. A new methodology to determine the more precise velocity for Non-ABS vehicle at braking onset were suggested.