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Effect of Triethylaluminum/Transition-Metal Ratio on the Physical Properties and Chemical Composition Distributions of Ethylene-Hexene Copolymers Produced by a $rac-Et(Ind)_2ZrCl_2/TiCl_4/MAO/SMB$ Catalyst
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  • Effect of Triethylaluminum/Transition-Metal Ratio on the Physical Properties and Chemical Composition Distributions of Ethylene-Hexene Copolymers Produced by a $rac-Et(Ind)_2ZrCl_2/TiCl_4/MAO/SMB$ Catalyst
  • Effect of Triethylaluminum/Transition-Metal Ratio on the Physical Properties and Chemical Composition Distributions of Ethylene-Hexene Copolymers Produced by a $rac-Et(Ind)_2ZrCl_2/TiCl_4/MAO/SMB$ Catalyst
저자명
Park. Hai-Woong,La. Kyung-Won,Song. In-Kyu,Chung. Jin-Suk
간행물명
Macromolecular research
권/호정보
2007년|15권 3호|pp.221-224 (4 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

A silica-magnesium bisupport (SMB) was prepared by a sol-gel method for use as a support for a metal-locene/Ziegler-Natta hybrid catalyst. The prepared $rac-Et(Ind)_2ZrCl_2/TiCl_4$/MAO(methylaluminoxane)/SMB catalyst was applied to the copolymerization of ethylene with l-hexene using a variable triethylaluminum (TEA)/transition-metal (Ti) ratio and fixed MAO/transition-metal (Zr) ratio. The effect of the Al(TEA)/Ti ratio on the physical properties and chemical composition distributions (CCDs) of the ethylene-hexene copolymers produced by the hybrid catalyst was investigated. In the ethylene-hexene copolymers, two melting temperatures attributed to the metal-locene and Ziegler-Natta catalysts were clearly observed. The number of CCD peaks was increased from six to seven and the temperature region in which the peaks for the short chain branches of the ethylene-hexene copolymer were distributed became lower as the Al(TEA)/Ti ratio was increased from 300 to 400. Furthermore, the temperature regions corresponding to the lamellas in the copolymer became lower and those corresponding to the small lamellas in the copolymer became higher as the Al(TEA)/Ti ratio was increased from 300 to 400. In the copolymer produced with Al(TEA)/Ti = 500, however, only four CCD peaks were observed and the short chain branches were poorly distributed.