[ $Li_+$ ]를 기반으로 하는 비수용액 전해질에서 Prussian blue가 degradation이 없이 구동할 수 있도록 소재를 design하고 제조하여 전기화학적 변색특성을 연구하였다. Prussian blue는 ITO가 코팅되어 있는 유리판위에 일정전류-전착법으로 코팅을 했고, 이 때 사용된 코팅 용액은 $FeCl_3,;K_3Fe(CN)_6$을 deionized water에 녹이고, HCl, KCl, LiCl을 각각 넣었다. 전기화학적 변색특성을 비교하기 위해 continuous와 pulse potential cycle 하는 동안 transmittance 변화를 in-situ He-Ne laser를 이용하여 측정하였고, electroactive layer thickness를 통해 degradation된 정도를 실험하였다.
The durability problem of Prussian blue in non-aqueous $Li_+$-based electrolytes has been due to the degradation of the Prussian blue electrode matrix during the insertion/extraction processes by $Li_+$. In this work, we designed and synthesised the Prussian blue without reducing the electrochromic performance in non-aqueous $Li_+$-based electrolytes. Prussian blue was electrodeposited on a glass which has ITO coating, and the coating solution is a mixture solution of $FeCl_3;and;K_3Fe(CN)_6$ with deionized water added HCl, KCl, and LiCl, respectively. The durability of Prussian blue was evaluated by an in-situ transmittance measurement during a continuous and pulse potential cycling test, and measured by electroactive layer thickness due to evaluating the degradation.
