This paper analyses the environmental effect of 100kw PV system installed in Tibet using Life Cycle Assessment(LCA). Then, energy payback time(EPT) and life-cycle CO2 emission rate are estimated based on life-cycle of the PV system. As a result of the estimation, 6 year of EPT and 20 g-C/kWh of CO2 emission rate are obtained. In China, average CO2 emission rate of fossil fuel power generation plant is 260 g-C/kWh. This shows that PV system would be very promising for global environmental issues. For advanced LCA, we need to collect detailed and various data about raw material of PV system.