The Gun-Oreinted Anti-Air Warfare(GOAAW) which is still one of the important weapon systems of the vessel like the patrol killer to confront air threats comprises the components of the combat system - Command & Control(C2), Ballistic Calculation Unit, Sensors and Guns. In this paper, the GOAAW process of the patrol killer combat system is analyzed with probability and simulated to evaluate the effectiveness and capability of the GOAAW. As a result of the simulation, the performance measures of the GOAAW are discussed in the functional and operational aspects of the combat system.