돈분폐수 처리수의 색도를 제거하기 위해 최적의 응집 조건에 대하여 평가하였다. 유출수의 용존 유기 탄소 농도는 227.3 mg/L, 색도는 2,430 CU, 탁도는 22.1 NTU, 그리고 UV$_{254}$는 3.7 cm$^{-1}$이었다. 유출수의 소수성 유기물은 55.3%, 반친수성 유기물은 17.4%, 그리고 친수성 유기물은 27.3%로 세분화하였다. 또한, 겉보기 분자량 분포는 0.5 K 이하, 0.5$sim$1 K, 1$sim$10 K, 10$sim$30 K 및 30 K 이상은 각각 74.2%, 7.3%, 5.5%, 7.1% 및 5.9%이었다. 최적의 pH 및 응집제 주입량을 결정하기 위해 유동전류계를 사용하였다. 황산알루미늄과 염화 제 2철의 최적 응집제 주입량 및 pH는 각각 5.84 mM, pH는 5.3이며, 9.25 mM, pH는 5.0이었다. 최적의 응집 조건에서 황산알루미늄과 염화 제 2철은 각각 91.9%와 98.7%로 높은 색도 제거 효율을 얻었다. 생물학적 처리를 거친 돈분폐수는 화학적인 응집으로 색도제거에 좋은 성과를 보여주었다.
This study was to evaluate the optimum conditions for chemical coagulation to remove color from the effluent of a piggery wastewater treatment process. The DOC concentration in the effluent was about 227.3 mg/L, color was 2,430 CU, turbidity was 22.1 NTU, and UV$_{254}$-absorbance was 3.7 cm$^{-1}$. The fractions of hydrophobic, transphilic, and hydrophilic substance of the effluent was about 55.3%, 17.4%, 27.3% respectively. Also, molecular weight cut-off(MWCO) of below 0.5 K, 0.5 K to 1 K, 1 K to 10 K, 10 K to 30 K, and over 30 K were 74.2%, 7.3%, 5.5%, 7.1%, and 5.9% respectively. SCD(streaming current Detector) was used to find out the optimum pH values and coagulant dosages. The optimum dosages and pH of Al$^{3+}$ were 5.84 mM and 5.3, while those of Fe$^{3+}$ were 9.25 mM and 5.0, respectively. At optimum conditions of coagulation, color removal efficiencies for aluminium sulfate and ferric chloride were as high as 91.9 and 98.7%, respectively. Chemical coagulation showed good performance to remove color from on biologically treated piggery wastewater.
