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Synthesis of Nanocrystalline TiO2 by Sol-Gel Combustion Hybrid Method and Its Application to Dye Solar Cells
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  • Synthesis of Nanocrystalline TiO2 by Sol-Gel Combustion Hybrid Method and Its Application to Dye Solar Cells
  • Synthesis of Nanocrystalline TiO2 by Sol-Gel Combustion Hybrid Method and Its Application to Dye Solar Cells
저자명
Han. Chi-Hwan,Lee. Hak-Soo,Han. Sang-Do
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2008년|29권 8호|pp.1495-1498 (4 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

$TiO_2$ nanopowders were synthesized by new sol-gel combustion hybrid method using acetylene black as a fuel. The dried gels exhibited autocatalytic combustion behaviour. $TiO_2$ nanopowders with an anatase structure and a narrow size distribution were obtained at 400-600 ${^{circ}C}$. Their crystal structures were examined by powder Xray diffraction (XRD) and their morphology and crystal size were investigated by scanning electron microscopy (SEM). The crystal size of the nanopowders was found to be in the range of 15-20 nm. $TiO_2$ powders synthesized at 500 ${^{circ}C}$ and 600 ${^{circ}C}$ were applied to a dye solar cell. An efficiency of 5.2% for the conversion of solar energy to electricity ($J_{sc}$ = 11.79 mA/$cm^2$, $V_{oc}$ = 0.73 V, and FF = 0.58) was obtained for an AM 1.5 irradiation (100 mW/$cm^2$) using the $TiO_2$ nanopowder synthesized by the sol-gel combustion hybrid method at 500 ${^{circ}C}$.