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Nonlinear Entropy Production in a Reversible Oregonator Model
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  • Nonlinear Entropy Production in a Reversible Oregonator Model
  • Nonlinear Entropy Production in a Reversible Oregonator Model
저자명
Basavaraja. C.,Pierson. R.,Park. Seung-Hyun,Jeon. Eun-Ji,Huh. Do-Sung
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2008년|29권 5호|pp.1051-1054 (4 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The entropy production in a non-equilibrium state based on the reversible Oregonator model of the Belousov-Zhabotinskii (BZ) reaction system has been studied. The reaction affinity and the reaction rate for the individual steps have been calculated by varying the concentrations of key variables in the system. The result shows a linear relationship between the reaction affinity and the reaction rate in the given concentration range. However, the overall entropy calculated on the basic assumption that the entropy in a reaction system corresponds to the summation of a product of reaction affinity and reaction rate of individual steps shows a nonlinearity of the reaction system. The results well agrees with the fact that the entropy production is not linear or complicated function in a non-linear reaction system.