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튜브식 양극판의 침적공정이 전지 성능에 미치는 영향
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  • 튜브식 양극판의 침적공정이 전지 성능에 미치는 영향
  • The influence of the soaking in the manufacturing of positive tubular plates on the performance of lead-acid batteries
저자명
윤연섭,김병관,안상용,Yoon. Youn-Saup,Kim. Byung-Kuan,An. Sang-Yong
간행물명
한국유화학회지
권/호정보
2008년|25권 2호|pp.211-218 (8 pages)
발행정보
한국유화학회
파일정보
정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The performance of positive plates depends on the structure of the lead dioxide active mass. The positive active materials (PAM) consists of a skeleton, built up of agglomerates and macropores. Agglomerates, in their turn, comprise particles and micropores. This paper described a study conducted to determine the effects of different soaking times between the acid fill and formation stages of the tubular plate production. For the positive plates a lead oxide were filled into tubular bag with a red lead. After filling the positive plates were soaked in $H_2SO_4$ solution. X-ray diffraction(XRD), scanning electron microscopy(SEM) and electrical testing had been used to study the compositional and morphological aspects of the positive active material(PAM) just prior and after formation. Results indicate that PAM compositions were effected by the soaking time and acid density of $H_2SO_4$ solution. It can be seen that as the soaking time duration increases, $alpha$-PbO, $Pb_3O_4$, and Pb were all gradually sulphating. Composition of 3BS reached a maximum at around 3 h duration and $H_2SO_4$ of sp. gr. 1.10 on soaking. This results would suggest that the most beneficial conditions for soaking were the $H_2SO_4$ of sp. gr. 1.10 and 2 to 6 h of soaking.