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Synthesis of Modified Silane Acrylic Resins and Their Physical Properties as Weather-Resistant Coatings
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  • Synthesis of Modified Silane Acrylic Resins and Their Physical Properties as Weather-Resistant Coatings
  • Synthesis of Modified Silane Acrylic Resins and Their Physical Properties as Weather-Resistant Coatings
저자명
Yoo. Gyu-Yeol,Kim. Ji-Hyun,Park. Hong-Soo,Kim. Young-Geun,Kim. Seong-Kil
간행물명
한국유화학회지
권/호정보
2008년|25권 1호|pp.1-14 (14 pages)
발행정보
한국유화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

To prepare weather-resistant modified silane acrylic resin coatings for an architectural purpose, tetrapolymers were synthesized by radical polymerization. 3-Methacryloxypropyltrimethoxysilane (MPTS) as a silicone monomer and n-butyl acrylate, methyl methacrylate, and n-butyl methacrylate as acrylic monomers were used. The composition of monomers was adjusted to fix the glass transition temperature of acrylic polymer for $20^{circ}C$. The composition of MPTS in the synthesized polymer were varied from 10 wt% to 30 wt%. On the basis of synthesized resin amber paints were prepared and their physical properties and effects on weatherability were examined. The presence of MPTS in modified silane acrylic resins generally resulted in low molecular weight and broad molecular weight distribution, and also lowered the viscosity of the copolymers. The coated films prepared from these resins showed good and balanced properties in general. Adhesion to the substrate was outstanding in particular. Weatherability tests were carried out in three different types such as outdoor exposure, QUV, and SWO. The test results showed that the modified silane acrylic resins containing 30 wt% of MPTS had superior weathering properties.