This paper describes a Neural Network based PD control scheme for motion control of pneumatic servo cylinder. Pneumatic systems have inherent nonlinearities such as compressibility of air and nonlinear frictions present in cylinder. The conventional linear controller is limited in some applications where the affection of nonlinear factor is dominant. A self-excited oscillation method is applied to derive the dynamic design parameters of linear model. Based on the parameters thus identified, a PD feedback compensator is designed first and then a neural network is incorporated. The experiments of a trajectory tracking control using the proposed control scheme are performed and a significant reduction in tracking error is achieved by comparing with those of a PD control.