This paper describes a message model based on XML (eXtensible Markup Language) to present real-time data from sensors and instruments at manufacturing processes for web service. HTML (Hyper Text Markup Language) is inadequate for describing real-time data from process control plants while it is suitable for displaying non-real-time multimedia data on web. For XML-based web service of process data, XML format for the data presentation was proposed after investigating data of various instruments at steel-making plants. Considering transmission delay inevitably caused from increased message length and processing delay from transformation of raw data into defined format, which was critical for operation of a real-time system, its performance was evaluated by simulation. In the simulation, we assumed two implementation models for conducting the transformation function. In one model, transformation was done at an SCC (Supervisory Control Computer) after receiving real-time data from instruments. In the other model, transformation had been carried out at instruments before the data were transmitted to the SCC. Various tests had been conducted under different conditions of offered loads and data lengths and their results were described.