In general, ground pollution can be classified with soil pollution and underground water pollution. And ground pollution contaminates the land with garbage dumps and other harmful waste products as heavy metals that can also eventually enter our water supply. This study was conducted to define a characteristics of the electrical resistivity and the permittivity of weathered soil that was contaminated with heavy metals as Mercury and Arsenic. It is not easy whether contamination of soil as subsurface contamination is decided or not and at an early stage especially do that. Therefore the electrical resistivity and the permittivity were used to make up for this defects. These methods are more economical and more effective than the existing methods. And variation of the electrical resistivity and the permittivity values were found against the change of concentration of Mercury and Arsenic aqueous solutions and measuring frequency. These analyzed results indicate that the electrical resistivity and the permittivity tend to decrease against increasing measuring frequency. The electrical resistivity and the permittivity are also found to show the function of frequency.