Currently, due to the severity of world-wide air pollution by substances emitted from vehicles, emission control is being enforced more strictly, and it is expected that the regulation requirements for emission will become even more severe. A new concept combustion technology that can reduce the Nitrogen oxides (NOx) and PM in relation to combustion is urgently required. As a core combustion technology among new combustion technologies for the next generation engine, the homogenous charge compression ignition (HCCI) is expanding its application range by adopting a multiple combustion mode, a catalyst, direct fuel injection and partially premixed charge compression ignition combustion using the split injection method. This paper used a split injection method in order to apply the partially premixed charge compression ignition combustion method without significantly altering engine specifications of the multiple combustion mode and practicality by referring to the results of studies on the HCCI engine. Furthermore, the effects of the ratio of the fuel injection amount on split injection are investigated. From the test results, the adequate combination of the ratio of the fuel injection amount for the split injection method has some benefit on exhaust and fuel economy performance in a naturally aspirated single cylinder diesel engine.