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Synthesis of a Novel Nitrogen-Phosphorus Flame Retardant Based on Phosphoramidate and Its Application to PC, PBT, EVA, and ABS
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  • Synthesis of a Novel Nitrogen-Phosphorus Flame Retardant Based on Phosphoramidate and Its Application to PC, PBT, EVA, and ABS
  • Synthesis of a Novel Nitrogen-Phosphorus Flame Retardant Based on Phosphoramidate and Its Application to PC, PBT, EVA, and ABS
저자명
Nguyen. Congtranh,Kim. Jin-Hwan
간행물명
Macromolecular research
권/호정보
2008년|16권 7호|pp.620-625 (6 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

A novel nitrogen-phosphorus compound, diphenyl piperazine-1,4-diylbis(methylphosphinate)(DPPMP) was synthesized via a two step reaction and its flame retarding efficiency as a single component additive was investigated. The success of synthesis was confirmed by FTIR and $^1H$ and $^{31}P$ NMR analysis. The product was mixed with polycarbonate (PC), poly(butylene terephtalate) (PBT), ethylene-vinyl-acetate copolymer (EVA), and acrylonitrile-butadiene-styrene copolymer (ABS). The flame-retarding efficiency was evaluated using the limiting oxygen index (LOI) and the UL-94 vertical test methods. The addition of DPPMP enhanced the flame retardancy of the polymers and the V-0 ratings were obtained for the polymers examined in this study at a loading of 7-30 wt%. The gas-phase flame retardancy mode of action was suggested for this material from the thermogrametry experiment results.