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Mechanical Behavior of Shape Memory Fibers Spun from Nanoclay-Tethered Polyurethanes
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  • Mechanical Behavior of Shape Memory Fibers Spun from Nanoclay-Tethered Polyurethanes
  • Mechanical Behavior of Shape Memory Fibers Spun from Nanoclay-Tethered Polyurethanes
저자명
Hong. Seok-Jin,Yu. Woong-Ryeol,Youk. Ji-Ho
간행물명
Macromolecular research
권/호정보
2008년|16권 7호|pp.644-650 (7 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

This study examined the effect of nanoclays on the shape memory behavior of polyurethane (PU) in fibrous form. A cation was introduced into the PU molecules to disperse the organo-nanoclay (MMT) into poly($varepsilon$-caprolactone) (PCL)-based PU (PCL-PU). The MMT/PCL-PU nanocomposites were then spun into fibers through melt-processing. The shape memory performance of the spun fibers was examined using a variety of thermo-mechanical tests including a new method to determine the transition temperature of shape memory polymers. The MMTs showed an improved the fixity strain rate of the MMT /PCL- PU fibers but a slight decrease in their recovery strain rate. This was explained by the limited movement of PU molecules due to the presence of nanoclays. The shape memory performance of the MMT/PCL-PU fibers was not enhanced significantly by the nanoclays. However, their recovery power was improved significantly up to a strain of approximately 50%.