Direct measurements of four radiative components at air-sea boundary layer were conducted in the southern Yellow Sea during three cruises (seasons) in 2007. Simultaneous observations of meteorological (cloud cover, air temperature and humidity) and oceanographic (sea surface temperature) parameters were carried out. Observational results of radiative fluxes and meteorological and oceanographic parameters are presented. Mean diurnal cycles of four radiative components, net radiation, and sea surface albedo are calculated to achieve averages in different seasons. Net radiative fluxes in three seasons (winter, spring, autumn) are 8, 146, $60;W/m^2$, respectively. Comparisons between the observed radiative fluxes and those estimated with formulas are taken.