In this paper, we analyzed the physical and thermodynamic characteristics of fog by using the integrated water vapor (IWV) from Global Positioning System (GPS) networks and the regular observation data of meteorological stations in GPS sites. The cases of a radiation and an advection fog were selected as samples, the conversions of water substance from the water vapor to cloud water in fog were detected by the Bulk Water-Continuity Model, and the pattern analysis is adapted on GPS IWV, temperature, wind and relative humidity. Under the specific hypothesis (saturation and stable), GPS IWV could detect quantitatively the phase changing between the water vapor and cloud water content with condensation/evaporation during the formation and dissipation of fog. After it reaches to the saturation, the relative humidity can be a limited indicator for fog. However, GPS IWV can detect the status change of fog even after the saturation. It has indicated that GPS IWV could be a new observing technique for the processes of the fog formation and the dissipation.