We study on the practical privacy-preserving techniques by matrix-based randomization approach. We clearly examine the relationship between the two parameters associated with the measure of privacy breach and the condition number of matrix in order to achieve the optimal transition matrix. We propose a simple formula for efficiently calculating the inverse of transition matrix which are needed in the re-construction process of random substitution algorithm, and deduce some useful connections among standard error and another parameters by obtaining condition numbers according to norms of matrix and the expectation and variance of the transformed data. Moreover we give some experimental results about our theoretical expressions by implementing random substitution algorithm.