5-axis NC machining has a good advantage of the accessibility of tool motion by adding two rotary axes. It offers numerous advantages such as expanding machining fields in parts of turbo machineries like impeller, propeller, turbine blade and rotor, reasonable tool employment and great reduction of the set-up process. However, as adding two rotary axes, it is difficult to choose suitable machining conditions in terms of tool path, tool posture, feedrate control at a tool tip and post-processing. Therefore in this paper, it is proposed to decide suitable machining condition through an experimental method such as adopting various tool paths, tool postures, and feedrate types. Machining experiment on AL7075 for impeller is performed to define suitable machining condition, and measurement of surface roughness on machined surfaces depended on each machining condition is performed. By defining suitable machining condition, we should have conclusion as improving the surface quality in the aspect of surface roughness and machined shape of surface.