The output power of photovoltaic(PV) generation system is strongly affected by weather conditions. To make up for the defect of solar energy, energy storages such as battery and electrolyzer are usually integrated with photovoltaic cell. This paper focuses on the way to store energy surplus with battery and electrolyzer and to provide energy with battery. Photovoltaic generation system is modeled with PV cell, DC/DC converter, DC/AC inverter, battery and electrolyzer. The operation algorithm to regulate PV output power with battery and electrolyzer is suggested. The simulation results show that battery and electrolyzer effectively cooperate with each other to compensate the fluctuation of PV generation system.