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The Rapid and Efficient Synthesis of Bromohydrins from Olefins under HBr/H2O2 System by Visible Light Induced
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  • The Rapid and Efficient Synthesis of Bromohydrins from Olefins under HBr/H2O2 System by Visible Light Induced
  • The Rapid and Efficient Synthesis of Bromohydrins from Olefins under HBr/H2O2 System by Visible Light Induced
저자명
Tang. Rui-Ren,Gong. Nian-Hua
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2009년|30권 8호|pp.1832-1834 (3 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

A simple and safe method has been presented for conversion of olefins into bromohydrins using hydrogen bromide and hydrogen peroxide as bromide source by visible light induced within a very short time to get high yield bromohydrins along with a little mount dibromo-product. In this paper, cyclohexene is firstly carried out as the model substrate and investigated the bromination under HBr/$H_2O_2$ system using 150 W incandescent light irradiated in C$Cl_4$ within short time to get good yield of 2-bromocyclohexanol along with a little mount of 1,2-dibromocyclohexane; then, a series of alkenes are brominated to corresponding bromohydrins using the same protocol.