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The Effects of LaF3 Coating on the Electrochemical Property of Li[Ni0.3Co0.4Mn0.3]O2 Cathode Material
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  • The Effects of LaF3 Coating on the Electrochemical Property of Li[Ni0.3Co0.4Mn0.3]O2 Cathode Material
  • The Effects of LaF3 Coating on the Electrochemical Property of Li[Ni0.3Co0.4Mn0.3]O2 Cathode Material
저자명
Yun. Su-Hyun,Kim. Seuk-Buom,Park. Yong-Joon
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2009년|30권 11호|pp.2584-2588 (5 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The effect of $LaF_3$ coating on the structural and electrochemical properties of $Li[Ni_{0.3}Co_{0.4}Mn_{0.3}]O_{2}$ cathodes was investigated using XRD, SEM, TEM, and a cycler. The coating layer consisted of nano-sized particles attached nonuniformly to the surface of pristine powder. Despite the surface coating treatment, phase difference by $LaF_3$ coating was not detected. The discharge capacities of coated electrodes were a little lower than that of pristine sample at a 1 C rate. However, as the C rate increases, the capacity retention of the coated sample becomes obviously superior to that of the pristine sample. The cyclic performances of the electrodes in the voltage range of 4.8 $sim$ 3.0 V were also improved by the surface coating. Such enhancement is attributed to the presence of the $LaF_3$ coating layer, which effectively suppressd the reaction between electrodes and electrolytes on the surface of the $Li[Ni_{0.3}Co_{0.4}Mn_{0.3}]O_{2}$ electrode.