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A Quartz Tube Based Ag/Ag+ Reference Electrode with a Tungsten Tip Junction for an Electrochemical Study in Molten Salts
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  • A Quartz Tube Based Ag/Ag+ Reference Electrode with a Tungsten Tip Junction for an Electrochemical Study in Molten Salts
  • A Quartz Tube Based Ag/Ag+ Reference Electrode with a Tungsten Tip Junction for an Electrochemical Study in Molten Salts
저자명
Park. Y.J.,Jung. Y.J.,Min. S.K.,Cho. Y.H.,Im. H.J.,Yeon. J.W.,Song. K.
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2009년|30권 1호|pp.133-136 (4 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

A newly designed Ag/$Ag^+$ reference electrode in a quartz tube with a tungsten tip junction (W-tip-Quartz- REF) was fabricated and its electrochemical performance was compared with a conventional Pyrex tube-based Ag/$Ag^+$ reference electrode (Py-REF). The results of the electrochemical potential measurements with the W-tip-Quartz- REF and the Py-REF in the LiCl-KCl eutectic melts for a wide temperature range proved that the oxide layer on the surface of the tungsten metal tip provided a high ionic conduction. Stability of our newly designed W-tip- Quartz-REF was tested by measuring a junction potential for 12 hours at 700${^{circ}C}$. The results of the cyclic voltammetric measurement indicated that the Ag/$Ag^+$ reference electrode in the quartz tube with a tungsten tip junction can provide a good performance for a wide temperature range.