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Dispersion of Li[Ni0.2Li0.2Mn0.6]O2 Powder by Surfactant for High-power Li-ion Cell
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  • Dispersion of Li[Ni0.2Li0.2Mn0.6]O2 Powder by Surfactant for High-power Li-ion Cell
  • Dispersion of Li[Ni0.2Li0.2Mn0.6]O2 Powder by Surfactant for High-power Li-ion Cell
저자명
Yun. Su-Hyun,Park. Yong-Joon
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2009년|30권 7호|pp.1598-1602 (5 pages)
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대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The particle size of Li[$Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ cathode powder was controlled effectively by dispersion using lauric acid as a surfactant. The samples treated by lauric acid showed smaller particles of approximately half the original size compared to the particles of a pristine sample. A structural change due to the dispersion of Li[$Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ powder was not detected. The rate performance of the Li[$Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ cathode was improved by dispersion using lauric acid, which was likely due to the decrease of the particle size. In particular, a sample dispersed pristine powder using lauric acid (L2) presented a greatly enhanced discharge capacity and capacity retention at a high C rate. The discharge capacity of a pristine sample was only 133 m$Ahg^{-1}$ (3C rate) and 96 m$Ahg^{-1}$ (12C rate) at the tenth cycle. In contrast, the L2 electrode delivered higher discharge capacities of 160 m$Ahg^{-1}$ (3C rate) and 129 m$Ahg^{-1}$ (12C rate) at the tenth cycle. The capacity retention at a rate of 12C/2C was also enhanced from ~ 45% (pristine sample) to 57% (L2) by treatment with lauric acid.