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Luminescent Polynorbornene/Quantum Dot Composite Nanorods and Nanotubes Prepared from AAO Membrane Templates
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  • Luminescent Polynorbornene/Quantum Dot Composite Nanorods and Nanotubes Prepared from AAO Membrane Templates
  • Luminescent Polynorbornene/Quantum Dot Composite Nanorods and Nanotubes Prepared from AAO Membrane Templates
저자명
Oh. Se-Won,Cho. Young-Hyun,Char. Kook-Heon
간행물명
Macromolecular research
권/호정보
2009년|17권 12호|pp.995-1002 (8 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Luminescent polynorbornene (PNB)/quantum dot (CdSe@ZnS; QD) composite nanorods and nanotubes were successfully prepared using anodic aluminum oxide (AAO) membranes of various pore sizes as templates. To protect QDs with high quantum yield from quenching during the phosphoric acid treatment used to remove the AAO templates, chemically stable and optically clear norbornene-maleic anhydride copolymers (P(NB-r-MA)) were employed as a capping agent for QDs. The amine-terminated QDs reacted with maleic anhydride moieties in P(NB-r-MA) to form PNB-grafted QDs. The chemical- and photo-stability of QDs encapsulated with PNB copolymers were investigated by photoluminescence (PL) spectroscopy. By varying the pore size of the AAO templates from 40 to 380 urn, PNB/QD composite nanorods or nanotubes were obtained with a good dispersion of QDs in the PNB matrix.