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방전플라즈마 소결에 의한 자기 통전식 SiC계 세라믹 발열체 개발
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  • 방전플라즈마 소결에 의한 자기 통전식 SiC계 세라믹 발열체 개발
저자명
신용덕,최원석,고태헌,이정훈,주진영,Shin. Yong-Deok,Choi. Won-Seok,Ko. Tae-Hun,Lee. Jung-Hoon,Ju. Jin-Young
간행물명
전기학회논문지= The Transactions of the Korean Institute of Electrical Engineers
권/호정보
2009년|58권 4호|pp.770-776 (7 pages)
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대한전기학회
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정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The composites were fabricated by adding 0, 15, 30, 45[vol.%] $ZrB_2$ powders as a second phase to SiC matrix. The physical, mechanical and electrical properties of electroconductive SiC ceramic composites by spark plasma sintering(SPS) were investigated. Reactions between ${eta}$-SiC and $ZrB_2$ were not observed in the XRD and the phase analysis of the electroconductive SiC ceramic composites. The relative density of mono ${eta}$-SiC, ${eta}$-SiC+15[vol.%]$ZrB_2$, ${eta}$-SiC+30[vol.%]$ZrB_2$ and ${eta}$-SiC+45[vol.%]$ZrB_2$ composites are respectively 99.24[%], 87.53[%], 96.41[%] and 98.11[%] Phase analysis of the electroconductive SiC ceramic composites by XRD revealed mostly of ${eta}$-SiC, $ZrB_2$ and weakly of $ZrO_2$ phase. The flexural strength showed the lowest of 114.44[MPa] for ${eta}$-SiC+15[vol.%]$ZrB_2$ powders and showed the highest of 210.75[MPa] for composite no added with $ZrB_2$ powders at room temperature. The trend of the mechanical properties of the electroconductive SiC ceramic composites is accorded with the trend of the relative density. The electrical resistivity of the electroconductive SiC ceramic composites decreased with increased $ZrB_2$ contents. The electrical resistivity of mono ${eta}$-SiC, ${eta}$-SiC+15[vol.%]$ZrB_2$, ${eta}$-SiC+30[vol.%]$ZrB_2$ and ${eta}$-SiC+45[vol.%]$ZrB_2$ composites are respectively $4.57{ imes}10^{-1},;2.13{ imes}10^{-1},;2.68{ imes}10^{-2};and;1.99{ imes}10^{-2}[{Omega}{cdot}cm]$ at room temperature. The electrical resistivity of mono ${eta}$-SiC and ${eta}$-SiC+15[vol.%]$ZrB_2$ are negative temperature coefficient resistance(NTCR) in temperature ranges from $25[^{circ}C];to; 100[^{circ}C]$. The electrical resistivity of ${eta}$-SiC+30[vol.%]$ZrB_2$ and ${eta}$-SiC+45[vol.%]ZrB_2$ are positive temperature coefficient resistance(PTCR) in temperature ranges from $25[^{circ}C];to;100[^{circ}C]$. It is convinced that ${eta}$-SiC+30[vol.%]$ZrB_2$ composites by SPS for heater or ignitors can be applied.